175202-55-8Relevant articles and documents
Introduction of Molecular Building Blocks to Improve the Stability of Metal-Organic Frameworks for Efficient Mercury Removal
Jiang, Shu-Yi,He, Wen-Wen,Li, Shun-Li,Su, Zhong-Min,Lan, Ya-Qian
supporting information, p. 6118 - 6123 (2018/05/29)
With expanding human needs, many heavy metals were mined, smelted, processed, and manufactured for commercialization, which caused serious environmental pollutions. Currently, many adsorption materials are applied in the field of adsorption of heavy metals. Among them, the principle of many mercury adsorbents is based on the interaction between mercury and sulfur. Here, a S-containing metal-organic framework NENU-400 was synthesized for effective mercury extraction. Unfortunately, the skeleton of NENU-400 collapsed easily when exposed to the mercury liquid solution. To improve the stability, a synthetic strategy installing molecular building blocks (MBBs) into the channels was used. Modified by the MBBs, a more stable nanoporous framework was synthesized, which not only exhibits a high capacity of saturation mercury uptake but also shows high selectivity and efficient recyclability.
Phenyl Groups Result in the Highest Benzene Storage and Most Efficient Desulfurization in a Series of Isostructural Metal-Organic Frameworks
He, Wen-Wen,Yang, Guang-Sheng,Tang, Yu-Jia,Li, Shun-Li,Zhang, Shu-Ran,Su, Zhong-Min,Lan, Ya-Qian
supporting information, p. 9784 - 9789 (2015/06/30)
A series of isoreticular metal-organic frameworks (MOFs; NENU-511-NENU-514), which all have high surface areas and strong adsorption capacities, have been successfully constructed by using mixed ligands. NENU-513 has the highest benzene capacity of 1687 m
Efficient one pot preparation of variously substituted thieno[2,3-b]thiophene
Comel,Kirsch
, p. 1167 - 1171 (2007/10/03)
An efficient one pot access to variously substituted thieno[2,3-b]thiophene is described. The title compounds were obtained from 1,3-dicarbonyl or equivalent compounds, carbon disulfide and halomethyl derivatives in good to high yields and fully characterized.