175519-12-7

Basic information

• Product Name: fullerene
• CAS NO: 175519-12-7
• Molecular Weight: 720.66
• Mol File: 175519-12-7.mol
• Article Data: 98

Chemical Properties

• CAS DataBase Reference: fullerene(CAS DataBase Reference)
• NIST Chemistry Reference: fullerene(175519-12-7)
• EPA Substance Registry System: fullerene(175519-12-7)

Safety Data

• Hazardous Substances Data: 175519-12-7(Hazardous Substances Data)

Upstream product

• 141197-61-7 [76]fullerene 
• 10099-58-8 lanthanum(III) chloride 
• 13463-40-6 iron pentacarbonyl 
• 187737-37-7 propene 
• 7440-44-0 pyrographite 
• 1120395-94-9 3,8,13-tribromo-5,10,15-tris-naphthalen-2-ylmethylene-10,15-dihydro-5H-diindeno[1,2-a:1',2'-c]fluorene 
• 106-99-0 buta-1,3-diene 
• 67-66-3 chloroform 
• 7440-05-3 palladium 
• 307924-49-8 endo,endo-(m-phenylenedimethyl) 61,62-bis(N-diphenylmethylideneamino)-1,2:16,17-bis(methano)[60]fullerene-61,62-dicarboxylate 
• 307924-48-7 endo,endo-(m-phenylenedimethyl) 61,62-bis(N-diphenylmethylideneamino)-1,2:34,35-bis(methano)[60]fullerene-61,62-dicarboxylate 
• 100-39-0 benzyl bromide 

Downstream Products

• 142482-13-1 1,2-Dihydro<60>fullerene 
• 151872-44-5 N-Methylfulleropyrrolidine 
• 150493-27-9 ethyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate 
• 161432-01-5 1,2-dihydrofullerene functionalized with ethylester acetate group 

Relevant articles and documents

Significant promotional effect of CCl4 on fullerene yield in the graphite arc-discharge reaction

Addition of a small quantity (～3%) of CCl4 to the He atmosphere of the graphite arc-discharge reaction revealed a marked increase in fullerene yield.

Stereoselective synthesis of amino-substituted cyclopentafullerenes promoted by magnesium perchlorate/ferric perchlorate

A facile one-step reaction of [60]fullerene with cinnamaldehydes and amines promoted by magnesium perchlorate/ferric perchlorate under air conditions afforded a series of rare amino-substituted cyclopentafullerenes in moderate to good yields. Stereoselectivity was readily achieved. Secondary amines exclusively produced N,N-disubstituted cyclopentafullerenes as cis isomers, while arylamines gave N-monosubstituted cyclopentafullerenes with a preference of cis isomers as major products. N-Monosubstituted cyclopentafullerenes could be further converted into other scarce cyclopentafullerenes in the presence of acid chloride or paraformaldehyde. A possible reaction pathway was proposed to elucidate the formation of amino-substituted cyclopentafullerenes.

Lewis base-catalyzed double nucleophilic substitution reaction of N-tosylaziridinofullerene with thioureas or guanidines

Lewis base-catalyzed double nucleophilic substitution reaction of N-tosylaziridinofullerene with thioureas or guanidines affords the fullerothiazolidin-2-imine or fulleroimidazolidin-2-imine derivatives, respectively. In the case of unsymmetrical thiourea