17582-85-3

Basic information

• Product Name: Benzene, 1-(1,1-dimethylethyl)-4-(1-phenylethenyl)-
• CAS NO: 17582-85-3
• Molecular Formula: C18H20
• Molecular Weight: 236.357
• Mol File: 17582-85-3.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,1-dimethylethyl)-4-(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,1-dimethylethyl)-4-(1-phenylethenyl)-(17582-85-3)
• EPA Substance Registry System: Benzene, 1-(1,1-dimethylethyl)-4-(1-phenylethenyl)-(17582-85-3)

Safety Data

• Hazardous Substances Data: 17582-85-3(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 22679-54-5 4-tert-butylbenzophenone 
• 98-80-6 phenylboronic acid 
• 123324-71-0 p-tert-butylphenylboronic acid 
• 536-74-3 phenylacetylene 
• 3262-89-3 triphenylboroxine 
• 943-27-1 4'-t-butylacetophenone 
• 98-86-2 acetophenone 
• 14428-98-9 N-benzyl-N-(1-phenylethylidene)amine 
• 90006-76-1 3-methyl-3-phenyl-diaziridine 
• 100-42-5 styrene 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 2206-94-2 1-acetoxy-1-phenylethene 
• 1005197-05-6 4-tert-butylphenyl 1,1,2,2-tetrafluoroethanesulfonate 

Downstream Products

• 22679-54-5 4-tert-butylbenzophenone 
• 94788-62-2 1-(tert-butyl)-4-(1-phenylethyl)benzene 
• 124419-83-6 1,3-Bis(4-tert-butylphenyl)-1,3-diphenyl-1-propen 

Relevant articles and documents

Deaminative carbonylative coupling of alkylamines with styrenes under transition-metal-free conditions

A transition-metal-free deaminative carbonylation of alkylamines with styrenes has been developed. The reaction shows good functional group compatibility and various α,β-unsaturated ketones were obtained in moderate to good yields. The alkyl radical generated from Katritzky salts via base-promoted C-N bond cleavage is one of the key intermediates in this reaction. This journal is

Metal-free oxidative cross-coupling of diazirines with arylboronic acids

We report herein a metal-free cross-coupling of diazirines with arylboronic acids under oxidative conditions. The reaction affords a series of substituted olefins. It is proposed that the interaction between the nitrogen on diazirine with arylboronic acid plays a key role in this transformation.

Regioselective Heck reaction of aliphatic olefins and aryl halides

A regioselective Heck reaction of aliphatic olefins and aryl bromides is realized at internal carbons of olefins. Methanol solvent promoted halide ionization from neutral arylpalladium halide complexes via hydrogen bonding, so as to create cationic aryl-Pd species for regioselective olefin insertion.