176248-72-9

Basic information

• Product Name: methyl 10-(tosyloxy)undecanoate
• CAS NO: 176248-72-9
• Molecular Weight: 370.51
• Mol File: 176248-72-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 10-(tosyloxy)undecanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 10-(tosyloxy)undecanoate(176248-72-9)
• EPA Substance Registry System: methyl 10-(tosyloxy)undecanoate(176248-72-9)

Safety Data

• Hazardous Substances Data: 176248-72-9(Hazardous Substances Data)

Upstream product

• 38460-95-6 undec-10-enoyl chloride 
• 111-81-9 Methyl 10-undecenoate 
• 54704-39-1 (+/-)-10-Hydroxyundecansaeure-methylester 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 68820-37-1 10-methylundecan-1-al 
• 20194-45-0 10-methyl-1-undecanol 

Relevant articles and documents

Cobalt-Catalyzed Intermolecular Markovnikov Hydroamination of Nonactivated Olefins: N2-Selective Alkylation of Benzotriazole

Cobalt-catalyzed Markovnikov-selective hydroamination of nonactivated olefins was developed. Hydrogen atom transfer from a catalytically generated cobalt(III)-hydride complex to the olefins proceeded regioselectively, and the nucleophilic addition of benzotriazoles occurred selectively at their N2-positions. The synthetic utility of the obtained N2-alkylated benzotriazoles as stable amine protecting groups under various reaction conditions was demonstrated, and the products were also transformed into primary amines by zinc-mediated reduction.