17627-49-5

Basic information

• Product Name: Menthone
• Synonyms: 5-Methyl-2-(1-methylethyl)cyclohexanone, trans-; AI3-11106; CCRIS 5747; Cyclohexan-1-one, 2-isopropyl-5-methyl-, racemic; Cyclohexanone, 5-methyl-2-(1-methylethyl)-, trans-; FEMA No. 2667; HSDB 1268; Menthone (natural); Menthone racemic; Neomenthone; p-Menthan-3-one racemic; p-Menthan-3-one, trans-; p-Menthone; trans-Menthan-3-one; (dl)-Menthone; Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2R,5S)-rel-; Cyclohexanone, 5-methyl-2-(1-methylethyl)-, trans-(+/-)-; p-Menthan-3-one, dl-; trans-Menthone; (2R,5S)-5-methyl-2-(propan-2-yl)cyclohexanone
• CAS NO: 17627-49-5
• Molecular Formula: C10H18O
• Molecular Weight: 154.24932
• EINECS: 201-941-1
• Mol File: 17627-49-5.mol
• Article Data: 479

Chemical Properties

• Boiling Point: 205°C at 760 mmHg
• Flash Point: 72.8°C
• Appearance: /
• Density: 0.881g/cm³
• Vapor Pressure: 0.256mmHg at 25°C
• Refractive Index: 1.442
• CAS DataBase Reference: Menthone(CAS DataBase Reference)
• NIST Chemistry Reference: Menthone(17627-49-5)
• EPA Substance Registry System: Menthone(17627-49-5)

Safety Data

• Hazard Codes: Xn:Harmful
• Statements: R22:; R36:; R43:; R52/53:
• Safety Statements: S26:; S36/37:; S61:
• Hazardous Substances Data: 17627-49-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-9H,4-6H2,1-3H3/t8-,9+/m0/s1

Upstream product

• 89-82-7 pulegone 
• 43209-90-1 6-isopropylcyclohex-2-en-1-one 
• 917-54-4 methyllithium 
• 89-78-1 menthol 
• 38462-22-5 2-(1-mercapto-1-methylethyl)-5-methylcyclohexanone 
• 89-81-6 piperitone 
• 37886-68-3 (-)-(E)-(1R,4S)-menthyl oxime 
• 586-82-3 (+/-)-4-isopropyl-1-methyl-3-cyclohexen-1-ol 
• 67-56-1 methanol 
• 63187-91-7 methone glycerin acetal 
• 491-09-8 3-terpinolenone 
• 2216-51-5 (-)-menthol 
• 89-79-2 Isopulegol 
• 2216-52-6 Neomenthol 

Downstream Products

• 18368-87-1 1-ethyl-2-isopropyl-5-methyl-cyclohexanol 
• 38618-25-6 2-Isopropyl-1,5-dimethyl-cyclohexanol 
• 18427-47-9 2,6-Dibromo-2-isopropyl-5-methylcyclohexanone 
• 7231-40-5 (+)-(1R,3S,4S)-neomenthylamine 
• 20752-34-5 neoisomenthol 
• 18368-90-6 2-Isopropyl-5-methyl-1-phenyl-cyclohexanol 
• 162551-92-0 3-isopropyl-6-methyl-2-oxo-cyclohexanecarboxylic acid 
• 83462-16-2 2-acetoxymenthone 
• 1686-42-6 p-menthan-3-one semicarbazone 
• 16934-77-3 Neoisomenthylamine 
• 100049-49-8 N-menthyl-formamide 
• 20706-69-8 (1S,3S,4R)-menthylamine 
• 18368-88-2 2-Isopropyl-5-methyl-1-propyl-cyclohexanol 
• 1678-82-6 trans-1,4-menthane 

Relevant articles and documents

O3/Pb(OAc)4: a new and efficient system for the oxidative cleavage of allyl alcohols

Allyl alcohols undergo oxidative cleavage, affording the corresponding carbonyl compounds in good yields, when treated with ozone-lead(IV) acetate under mild conditions.

(±)-Camphor sulfonic acid assisted IBX based oxidation of 1° and 2° alcohols

-

SBA-15 Supported 1-Methyl-2-azaadamanane N-Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcohol

Herein, we designed and synthesized an SBA-15 supported 1-methyl-2-azaadamanane N-oxyl (1-Me-AZADO) and investigated its catalytic performance for selective oxidation of alcohols under Anelli's conditions. The first example of immobilization of 1-Me-AZADO was very important to advance the oxgenation effectively because this supported N-oxyl has excellent catalytic activity for oxidation of alcohols to carbonyl compounds, and more importantly, it can be conveniently recovered and reused at least 6 times without significant effect on its catalytic efficiency.