176704-27-1

Basic information

• Product Name: (4-chlorophenyl)bis(2-methoxyphenyl)bismuthane
• CAS NO: 176704-27-1
• Molecular Weight: 534.795
• Mol File: 176704-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-chlorophenyl)bis(2-methoxyphenyl)bismuthane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-chlorophenyl)bis(2-methoxyphenyl)bismuthane(176704-27-1)
• EPA Substance Registry System: (4-chlorophenyl)bis(2-methoxyphenyl)bismuthane(176704-27-1)

Safety Data

• Hazardous Substances Data: 176704-27-1(Hazardous Substances Data)

Upstream product

• 873-77-8 (4-chlorphenyl)magnesium bromide 

Relevant articles and documents

A new convenient synthesis of triarylbismuthanes bearing three different aryl groups by the grignard arylation of unsymmetrical diarylbismuth triflate-hexamethylphosphoric triamide (HMPA) complexes

Triarylbismuthanes bearing three different aryl groups, Ar1Ar2Ar3Bi (4), have been conveniently synthesized by the action of aryl Grignard reagent Ar3-MgBr on unsymmetrical diarylbismuth triflate-HMPA complexes Ar1Ar2BiOTf(HMPA)2 (8), which are readily accessible by the selective cleavage of triarylbismuthanes Ar12Ar2Bi (7; Ar1 is more fugacious than Ar2) with trimethylsilyl triflate in the presence of HMPA.