177032-63-2Relevant articles and documents
3-vinyl-2,5-dihydrofuran derivatives via enyne metathesis
Rodriguez-Fernandez, M. Mercedes,Vuong, Sophie,Renoux, Brigitte,Len, Christophe
, p. 1703 - 1706 (2007)
Acyclic enynes having the alkyne moiety directly connected to the asymmetric carbon atom of an acetal were obtained in two steps. These reactive substrates were then subjected to ruthenium-catalyzed enyne metathesis to produce (5-ethoxy-4-vinyl-2,5-dihydr
A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence. A stereocontrolled synthesis of all four α-/β- and D-/L-C-nucleoside stereoisomers
Stambasky, Jan,Kapras, Votech,Stefko, Martin,Kysilka, Ondrej,Hocek, Michal,Malkov, Andrei V.,Kocovsky, Pavel
experimental part, p. 7781 - 7803 (2011/12/14)
Iridium(I)-catalyzed allylation of the enantiopure monoprotected copper(I) alkoxide, generated from (S)-5a, with the enantiopure allylic carbonates (R)-9a,b has been developed as the key step in a new approach to C-nucleoside analogues. The anomeric cente
A chemoenzymatic approach to the synthesis of the stereoisomers of a β-adrenergic receptor antagonist
Dallanoce, Clelia,De Amici, Marco,Carrea, Giacomo,Secundo, Francesco,Castellano, Sabrina,De Micheli, Carlo
, p. 2741 - 2751 (2007/10/03)
The four stereoisomers of Δ2-isoxazoline 2, a β-adrenergic receptor antagonist structurally related to Falintolol 1, were prepared by an enzyme-catalyzed kinetic resolution of the unsaturated secondary alcohol (±)-7 followed by its cycloadditio
