177568-10-4Relevant articles and documents
Asymmetric synthesis of stigmatellin and crocacin C
Infante-Rodriguez, Carolina,Domon, Lisianne,Breuilles, Pascal,Uguen, Daniel
, p. 308 - 326 (2015)
The crystalline sulfone 18 (X-ray analysis), prepared from the monoacetate product [i.e., (+)-12; 98.2% ee] of the lipase PS-catalyzed acetylation of anti,anti-2,4-dimethyl-1,3,5-pentantriol (19a), has been elaborated either to crocacin C (10) or stigmatellin (1), thereby providing a convenient divergent access to these two natural antibiotics.