17798-94-6Relevant articles and documents
NOVEL REACTIONS OF PENTACOORDINATE PHOSPHORUS SYSTEMS DERIVED FROM PYROCATECHOL
Skowronska, A.,Burski, J.,Krawczyk, E.,Pakulski, M.
, p. 119 - 126 (2007/10/02)
Monocyclic chlorophosphoranes 1 and 2 have been used as models for investigations of nucleophilic displacement reactions at the pentacoordinate phosphorus atom.The chlorine ligands of 1 and 2 can be exchanged by nucleophiles under very mild conditions.Synthesis of the pentacoordinate phosphorus systems 4 and 5 via the reactions of 1 and 2 with a variety of nucleophiles is demonstrated.Special attention is paid to the reactions of chlorophosphoranes with such nucleophiles as organic phosphorus acids and thiocyanates.