178391-26-9Relevant articles and documents
Diastereoselective synthesis of heterosubstituted organogembismetallic reagents. Application to a new propargylmetalation reaction of vinyl metals
Brasseur, Denis,Marek, Ilane,Normant, Jean-F.
, p. 7235 - 7250 (1996)
The allylzincation and propargylzincation of various γ-heterosubstituted vinyl metals proceed diastereoselectively. This represents a new synthetic approach to construct two or three adjacent stereogenic centers in acyclic systems.