17864-23-2

Basic information

• Product Name: Silane, [1,2,3-benzenetriyltris(oxy)]tris[trimethyl-
• Synonyms: 1,2,3-Tris(trimethylsilyloxy)benzol;1,2,3-tris(trimethylsiloxy)benzene;1,2,3-tris-trimethylsilanyloxy-benzene;1,2,3-Tris-trimethylsilyloxy-benzol
• CAS NO: 17864-23-2
• Molecular Formula: C15H30O3Si3
• Molecular Weight: 342.658
• Mol File: 17864-23-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Silane, [1,2,3-benzenetriyltris(oxy)]tris[trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [1,2,3-benzenetriyltris(oxy)]tris[trimethyl-(17864-23-2)
• EPA Substance Registry System: Silane, [1,2,3-benzenetriyltris(oxy)]tris[trimethyl-(17864-23-2)

Safety Data

• Hazardous Substances Data: 17864-23-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 87-66-1 2-hydroxyresorcinol 
• 3385-94-2 hexamethyldisilathiane 
• 55549-22-9 2,3-Bis-trimethylsilanyloxy-phenol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 55549-21-8 3-Trimethylsilanyloxy-benzene-1,2-diol 
• 25561-30-2 N,O-Bis(trimethylsilyl)trifluoroacetamide 

Downstream Products

• 87-66-1 2-hydroxyresorcinol 

Relevant articles and documents

Poly(4-vinylpyridine) catalyzed chemoselective O-TMS protection of alcohols and phenols and N-Boc protection of amines

Poly(4-vinylpyridine) (PVP) acts as an efficient and reusable catalyst for the selective and efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) and N-tert-butoxycarbonylation of amines with (Boc)2O. All reactions were performed under mild conditions in good to high yields. Iranian Chemical Society 2012.

Highly atom economical uncatalysed and I2-catalysed silylation of phenols, alcohols and carbohydrates, using HMDS under solvent-free reaction conditions (SFRC)

An uncatalysed silylation of phenols, regardless on the aggregate state and nature of the substituents with 0.55 equiv of HMDS under solvent-free reaction conditions (SFRC) at room temperature is reported. Sterically hindered phenols, carbohydrates and most of the alcohols additionally required a catalytic amount (up to 2 mol %) of iodine. The reaction protocol is very simple; obtaining a pure product, particularly of uncatalysed reactions, was frequently a completely solvent-free process.

Highly efficient and selective trimethylsilylation of alcohols and phenols with hexamethyldisilazane catalyzed by polystyrene-bound tin(IV) porphyrin

In the present work, investigation of the catalytic activity of tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [Sn IV(TNH2PP)(OTf)2], supported on chloromethylated polystyrene in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane is reported. The prepared catalyst was characterized by elemental analysis, FT-IR and diffuses reflectance UV-Vis spectroscopic methods. This catalyst was used for selective trimethylsilylation of different alcohols and phenols with HMDS, with short reaction times and high yields. Also the catalyst is of high reusability and stability, in that it was recovered several times without loss of its initial activity.