17865-32-6Relevant articles and documents
METHOD FOR PRODUCING ORGANOSILICON COMPOUND HAVING CYCLIC ALKYL GROUP
-
Paragraph 0022; 0025; 0028; 0031; 0034; 0035; 0036, (2019/01/06)
PROBLEM TO BE SOLVED: To provide a method for producing an organosilicon compound that can efficiently produce an organosilicon compound, particularly an organic silicon compound having a cyclic alkyl group. SOLUTION: A method according to the present inv
Practical conversion of chlorosilanes into alkoxysilanes without generating HCl
Wakabayashi, Ryutaro,Sugiura, Yasushi,Shibue, Toshimichi,Kuroda, Kazuyuki
supporting information; experimental part, p. 10708 - 10711 (2011/12/05)
Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results. Copyright