17961-91-0Relevant articles and documents
Rhodium-catalyzed alkenylation of nitriles via silicon-assisted C-CN bond cleavage
Kita, Yusuke,Tobisu, Mamoru,Chatani, Naoto
supporting information; experimental part, p. 1864 - 1867 (2010/10/02)
Rhodium-catalyzed Mizoroki-Heck type reaction of nitriles via the cleavage of C-C bonds is described. Orthogonal and iterative functionalizations of arenes were also demonstrated by combining the present and conventional halide-based cross-coupling reacti
Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane
McNeill, Eric,Barder, Timothy E.,Buchwald, Stephen L.
, p. 3785 - 3788 (2008/02/12)
A method for the palladium-catalyzed silylation of aryl chlorides has been developed. The method affords desired product in good yield, is tolerant of a variety of functional groups, and provides access to a wide variety of aryltrimethylsilanes from commercially available aryl chlorides. Additionally, a one-pot procedure that converts aryl chlorides into aryl iodides has been developed.