180069-66-3

Basic information

• Product Name: 4,4'-(1,4-dinitrobutane-2,3-diyl)bis(methoxybenzene)
• Synonyms: 4,4'-(1,4-dinitrobutane-2,3-diyl)bis(methoxybenzene)
• CAS NO: 180069-66-3
• Molecular Weight: 360.367
• Mol File: 180069-66-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4,4'-(1,4-dinitrobutane-2,3-diyl)bis(methoxybenzene)(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-(1,4-dinitrobutane-2,3-diyl)bis(methoxybenzene)(180069-66-3)
• EPA Substance Registry System: 4,4'-(1,4-dinitrobutane-2,3-diyl)bis(methoxybenzene)(180069-66-3)

Safety Data

• Hazardous Substances Data: 180069-66-3(Hazardous Substances Data)

Upstream product

• 3179-10-0 1-methoxy-4-(2-nitro-vinyl)-benzene 
• 3179-10-0 (E)-1-methoxy-4-(2-nitrovinyl)benzene 
• 89984-56-5 methyl manganese chloride 

Relevant articles and documents

N -heterocyclic carbene organocatalytic reductive β,β-coupling reactions of nitroalkenes via radical intermediates

An unprecedented N-heterocyclic carbene catalytic reductive β,β-carbon coupling of α,β-nitroalkenes, by using an organic substrate to mimic the one-electron oxidation role of the pyruvate ferredoxin oxidoreductase (PFOR) in living systems, has been develo

Additions of organomanganese reagents to conjugated nitroolefins

Additions of organomanganese reagents to aromatic and aliphatic conjugated nitroolefins were examined for the first time. In most cases reaction proceeded rapidly at -30°C. Unlike Mn reagents lacking β-hydrogens (Me, Ph), which lead to oxidative coupling and reductive dimerisation of nitrostyrenes, benzylmanganese chloride gives 1,4-addition in yields exceeding Grignard or Cu-assisted additions. At 0°C alkyl(Bu, Pr)-manganese reagents undergo an addition-migration-elimination process with nitrostyrenes providing a convenient and stereospecific entry into arylated trans-olefins.