18008-59-8

Basic information

• Product Name: 1-methyl-8-oxa-bicyclo[3.2.1]octane
• Synonyms: 1-methyl-8-oxa-bicyclo[3.2.1]octane
• CAS NO: 18008-59-8
• Molecular Weight: 126.199
• Mol File: 18008-59-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methyl-8-oxa-bicyclo[3.2.1]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-8-oxa-bicyclo[3.2.1]octane(18008-59-8)
• EPA Substance Registry System: 1-methyl-8-oxa-bicyclo[3.2.1]octane(18008-59-8)

Safety Data

• Hazardous Substances Data: 18008-59-8(Hazardous Substances Data)

Upstream product

• 82004-74-8 1-methylcycloheptyl hypochlorite 

Relevant articles and documents

FERROUS ION INDUCED DECOMPOSITION OF ALKYL HYPOCHLORITES

The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76percent.In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination.Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ο-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction.