18028-00-7Relevant articles and documents
Concerning the mechanism of the reductive cleavage of α-nitrocumene and cumyl chloride
Denney, Donald B.,Denney, Dorothy Z.,Fenelli, Steven P.
, p. 5397 - 5402 (1997)
The reductive cleavages of α-nitrocumene and cumyl chloride by sodium naphthalenide in tetrahydrofuran have been studied. It is concluded that the cumyl carbanion is the first intermediate formed in these reactions.
ORGANOMETALLIC COMPOUNDS IN ORGANIC SYNTHESIS-PART 17; REACTIONS OF TRICARBONYLCYCLOHEXADIENYLIRON SALTS WITH O-SILYLATED ENOLATES, ALLYL SILANES AND ASPECTS OF THEIR SYNTHETIC EQUIVALENTS
Birch, Arthur J.,Kelly, Lawrence F.,Narula, Acharan S.
, p. 1813 - 1824 (2007/10/02)
Efficient C-C bond formation results during reactions of O-silylated enolates and allyltrialkylsilanes with a range of tricarbonylcyclohexadienyliron salts to give tricarbonylcyclohexadieneiron complexes in good to excellent yields.This represents a new a