18028-01-8

Basic information

• Product Name: Silane, ethyldimethyl(2-phenylethyl)-
• CAS NO: 18028-01-8
• Molecular Formula: C12H20Si
• Molecular Weight: 192.376
• Mol File: 18028-01-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, ethyldimethyl(2-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, ethyldimethyl(2-phenylethyl)-(18028-01-8)
• EPA Substance Registry System: Silane, ethyldimethyl(2-phenylethyl)-(18028-01-8)

Safety Data

• Hazardous Substances Data: 18028-01-8(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 758-21-4 dimethylethylsilane 

Relevant articles and documents

Highly efficient B(C6F5)3-catalyzed hydrosilylation of olefins

A convenient and highly efficient method for the Lewis acid-catalyzed trans-selective hydrosilylation of alkenes has been developed. The mechanism of this novel protocol operates via direct addition of silylium type species across C=C bond followed by trapping of the resultant carbenium ion with boron-bound hydride. A number of diversely substituted silanes possessing both aryl and alkyl groups at silicon atom were efficiently prepared using this hydrosilylation methodology. The possibility to employ aryl-containing hydrosilanes in this reaction opens broad capabilities for the synthesis of alcohols via a trans-selective hydrosilylation/Tamao - Fleming oxidation sequence, complementary to the existing cis-selective hydroboration/oxidation protocol.

[Rh(Cod)Cl]2/Pph3?catalyzed dehydrogenative silylation of styrene derivatives with NBE as a hydrogen acceptor

Direct synthesis of arylalkenylsilanes by [Rh(COD)Cl]2/ PPh3-catalyzed dehydrogenative silylation of styrene derivatives with R3SiH (R = alkyl, alkoxy, aryl) was realized, in which norbornene (NBE) and PPh3 play a key role in achieving excellent selectivity in the formation of dehydrogenative silylation products. Moreover, this high-yielding transformation exhibits a broad substrate scope and good functional group tolerance.