180386-44-1Relevant articles and documents
Insertion of CO and CNR into tantalum-methyl bonds of imido(pentamethylcyclopentadienyl)tantalum complexes. X-ray crystal structures of [TaCp*(NR)-Me{η2-C(Me)=NR}] and [TaCp*Cl(O){η2-C(Me)=NR}] (R = 2,6-Me2C6H
Gómez, Manuel,Gómez-Sal, Pilar,Jiménez, Gerardo,Martín, Avelino,Royo, Pascual,Sánchez-Nieves, Javier
, p. 3579 - 3587 (2008/10/08)
Gómez, Manuel,Gómez-Sal, Pilar,Jiménez, Gerardo,Martín, Avelino,Royo, Pascual,Sánchez-Nieves, Javier
, p. 3579 - 3587 (2008/10/08)
[TaCp*Cl2{N(2,6-Me2C6H 3)}] reacts with 2 equiv of LiMe at -78 °C to give the imido dimethyl complex TaCp*Me2{N(2,6-Me2C6H3)} (1) in almost quantitative yield, whereas