1807-54-1

Basic information

• Product Name: Hydrazine, tetrakis(4-methoxyphenyl)-
• CAS NO: 1807-54-1
• Molecular Formula: C28H28N2O4
• Molecular Weight: 456.541
• Mol File: 1807-54-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Hydrazine, tetrakis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazine, tetrakis(4-methoxyphenyl)-(1807-54-1)
• EPA Substance Registry System: Hydrazine, tetrakis(4-methoxyphenyl)-(1807-54-1)

Safety Data

• Hazardous Substances Data: 1807-54-1(Hazardous Substances Data)

Usage

General Description

Hydrazine, tetrakis(4-methoxyphenyl)-, also known as AS4MP, is a chemical compound with the molecular formula C32H28N4O4. It is a symmetric molecule containing four 4-methoxyphenyl groups attached to a central hydrazine group. AS4MP is often used as a reducing agent in synthetic organic chemistry, particularly in the synthesis of pharmaceuticals and agrochemicals. It is also commonly used as a ligand in coordination chemistry, forming complexes with various metal ions. AS4MP is a solid at room temperature and is typically handled and stored using standard laboratory procedures for hazardous chemicals. However, it should be handled with caution due to its potential hazardous properties.

Upstream product

• 60-29-7 diethyl ether 
• 101-70-2 bis(4-methoxyphenyl)amine 

Downstream Products

• 2643-00-7 di-p-anisylnitroxide 
• 6947-36-0 N-nitrosodi(anisyl)amine 
• 101-70-2 bis(4-methoxyphenyl)amine 
• 31438-43-4 2,7-dimethoxy-5,10-bis-(4-methoxy-phenyl)-5,10-dihydro-phenazine 

Relevant articles and documents

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn=N, P, As)

The controlled release of well-defined radical species under mild conditions for subsequent use in selective reactions is an important and challenging task in synthetic chemistry. We show here that simple bismuth amide species [Bi(NAr2)3] readily release aminyl radicals [NAr2]. at ambient temperature in solution. These reactions yield the corresponding hydrazines, Ar2N?NAr2, as a result of highly selective N?N coupling. The exploitation of facile homolytic Bi?Pn bond cleavage for Pn?Pn bond formation was extended to higher homologues of the pnictogens (Pn=N–As): homoleptic bismuth amides mediate the highly selective dehydrocoupling of HPnR2 to give R2Pn?PnR2. Analyses by NMR and EPR spectroscopy, single-crystal X-ray diffraction, and DFT calculations reveal low Bi?N homolytic bond-dissociation energies, suggest radical coupling in the coordination sphere of bismuth, and reveal electronic and steric parameters as effective tools to control these reactions.

Kinetics of Oxidation of Unsubstituted and Substituted Diphenylamines by Alkaline Hexacyanoferrate(III)

Oxidation of unsubstituted and substituted diphenylamines by alkaline hexacyanoferrate(III) at constant ionic strength in aqueous methanol is first order each in and , and independent of in the range studied.The Hammet plot y