180736-79-2

Basic information

• Product Name: 2-[3-(2,2-dimethoxy-ethyl)-buta-1,3-dienyl]-1,3,3-trimethylcyclohexene
• Synonyms: 2-[3-(2,2-dimethoxy-ethyl)-buta-1,3-dienyl]-1,3,3-trimethylcyclohexene
• CAS NO: 180736-79-2
• Molecular Weight: 264.408
• Mol File: 180736-79-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-[3-(2,2-dimethoxy-ethyl)-buta-1,3-dienyl]-1,3,3-trimethylcyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[3-(2,2-dimethoxy-ethyl)-buta-1,3-dienyl]-1,3,3-trimethylcyclohexene(180736-79-2)
• EPA Substance Registry System: 2-[3-(2,2-dimethoxy-ethyl)-buta-1,3-dienyl]-1,3,3-trimethylcyclohexene(180736-79-2)

Safety Data

• Hazardous Substances Data: 180736-79-2(Hazardous Substances Data)

Upstream product

• 79-77-6 (E)-β-ionone 
• 180736-86-1 1-hydroxy-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-1,4-dien-3-one 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 85458-25-9 5,5-dimethoxy-1-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-1-en-3-one 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 379669-31-5 7-methylene-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,8-trien-1-ol 
• 379669-30-4 7-methylene-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,8-trienoic acid methyl ester 
• 304466-91-9 (3E,7E)-6-Methylene-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octa-3,7-dien-2-one 
• 259181-78-7 2-[(2E,4E,6E)-1,5-Dimethyl-7-(2,6,6-trimethyl-cyclohex-1-enyl)-hepta-2,4,6-trien-(E)-ylidene]-malonic acid monomethyl ester 
• 20013-34-7 acide-2-carboxy-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2E,4E,6E,8E-tetraenoique 
• 302-79-4 all-trans-retinoic-acid 
• 5560-99-6 (2X,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienal 
• 4759-48-2 13-cis-retinoic acid 
• 180736-80-5 (4E)-3-methylene-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-4-pentenal 

Relevant articles and documents

Syntheses of new 9- and 13-methylene isomers of retinal

Syntheses of new 9- and 13-methylene isomers of retinal via the '9-methylene-C-18 ketone' 1 or 'C-18 ketone' 2 are reported. (C) 2000 Published by Elsevier Science Ltd.

Stereoselective synthesis of 13Z retinoic acids via β-methylenealdehydes as synthons

A stereoselective synthesis of 13Z retinoic acids via β-methylenealdehydes is described. In methylene-de-oxo-bisubstitution reactions (Knoevenagel, Stobbe, etc.), these new synthons produce stereoselectively E olefins. Hence, a synthesis of 13Z retinoic acids is described, via a stereospecific monodecarboxylation of carboxy-14-retinoic acids.