181053-79-2

Basic information

• Product Name: ethyl (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienoate
• Synonyms: ethyl (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienoate
• CAS NO: 181053-79-2
• Molecular Weight: 448.678
• Mol File: 181053-79-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienoate(181053-79-2)
• EPA Substance Registry System: ethyl (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienoate(181053-79-2)

Safety Data

• Hazardous Substances Data: 181053-79-2(Hazardous Substances Data)

Upstream product

• 181053-71-4 (2E,6Z)-8-(tert-Butyl-dimethyl-silanyloxy)-4-dimethylamino-2,6-dimethyl-octa-2,6-dienoic acid ethyl ester 
• 181053-74-7 (3E,6Z)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(N,N-dimethyl-aminooxy)-2,6-dimethyl-octa-3,6-dienoic acid ethyl ester 
• 181053-73-6 ethyl (2E,4E,6Z)-8-tert-butyldimethylsiloxy-2,6-dimethylocta-2,4,6-trienoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 181053-78-1 ethyl (2E,4E,6Z)-8-hydroxy-2,6-dimethylocta-2,4,6-trienoate 

Downstream Products

• 463302-50-3 9-(2',6',6'-trimethylcyclohex-1'-enyl)-8-acetoxy-1-tert-butyldiphenylsiloxy-3,7-dimethyl-9-(p-tolylsulfonyl)nona-2Z,4E,6E-triene 
• 181053-77-0 9-(2',6',6'-trimethylcyclohex-1'-enyl)-8-acetoxy-3,7-dimethyl-9-(p-tolylsulfonyl)nona-2Z,4E,6E-trien-1-ol 
• 181053-76-9 (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trienal 
• 2052-63-3 2-cis-Vitamin-A 
• 181053-80-5 (2E,4E,6Z)-8-tert-butyldiphenylsiloxy-2,6-dimethylocta-2,4,6-trien-1-ol 

Relevant articles and documents

Highly Z selective synthesis of functionalized monoterpenoids via N-ylide [2,3]sigmatropic rearrangement and its application to 13-cis-retinol

Highly stereoselective elongation of a functionalized E isoprene unit on the Z terminal methyl of prenol was achieved by the N-ylide rearrangement of N-tiglyl-β-methallyldimethyl-ammonium salt. (E,Z)-Rearrangement product was converted into 13-cis-retinol via useful conjugated triene isoprenoid synthon.