18133-20-5Relevant articles and documents
A Novel heterospirocyclic 2H-azirin-3-amine as synthon for 3-aminothiolane-3-carboxylic acid
Raeber, Joelle L.,Brun, Kathrin A.,Heimgartner, Heinz
, p. 397 - 409 (2008/09/17)
The heterospirocyclic 2H-azirin-3-amine (9), i.e., N-methyl-N-phenyl-5-thia-1-azaspiro[2.4]hept-1-en-2-amine, was prepared from the commercially available thiolane-3-one (10) via the corresponding 3-carbonitrile (11) and 3-thiocarboxamide (14). This aziri