18138-87-9

Basic information

• Product Name: Furan, 2-(2-phenylethenyl)-, (Z)-
• CAS NO: 18138-87-9
• Molecular Formula: C12H10O
• Molecular Weight: 170.211
• Mol File: 18138-87-9.mol
• Article Data: 58

Chemical Properties

• CAS DataBase Reference: Furan, 2-(2-phenylethenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Furan, 2-(2-phenylethenyl)-, (Z)-(18138-87-9)
• EPA Substance Registry System: Furan, 2-(2-phenylethenyl)-, (Z)-(18138-87-9)

Safety Data

• Hazardous Substances Data: 18138-87-9(Hazardous Substances Data)

Upstream product

• 344775-40-2 2-((E)-But-1-en-3-ynyl)-3-phenyl-oxirane 
• 466686-19-1 (2E,4E)-6-acetoxy-6-phenylhexa-2,4-dienal 
• 19654-17-2 2-benzylthiobenzothiazole 
• 98-01-1 furfural 
• 72646-24-3 P-(benzylidene)methyldiphenylphosphorane 
• 100-52-7 benzaldehyde 
• 18138-86-8 (furan-2-yl)methyl triphenylphosphonium bromide 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 1080-32-6 O,O-diethyl benzylphosphonate 
• 67219-33-4 2-phenylmethanesulfonyl-benzothiazole 
• 108-94-1 cyclohexanone 
• 6921-34-2 benzylmagnesium chloride 
• 100-42-5 styrene 

Downstream Products

• 78443-36-4 5-((E)-Styryl)-furan-2-carbaldehyde 
• 1202-49-9 (E)-2-styrylfuran 
• 52341-99-8 5-phenethylfuran-2-carbaldehyde 
• 69443-82-9 2-Acetonyl-5-β-phenethylfuran 
• 69443-87-4 1-(2-Oxo-propyl)-4-phenethyl-7-oxa-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid dimethyl ester 
• 36707-30-9 2-(2-phenylethyl)furan 

Relevant articles and documents

A new insight into the push-pull effect of substituents via the stilbene-like model compounds

In this paper, authors report on 1-pyridyl-2-arylethenes, 1-furyl-2-arylethylenes, 1,2-diphenylpropylenes and substituted cinnamyl anilines as stilbene-like model compounds to investigate the factors dominating the push-pull effect of substituents via usi

A Solid-Phase Assisted Flow Approach to In Situ Wittig-Type Olefination Coupling

Described herein is the development of a continuous flow, solid-phase triphenylphosphine (PS-PPh3) assisted protocol to facilitate the in situ coupling of reciprocal pairs of halogen and carbonyl functionalised molecular pairs by a Wittig olefination within 15 mins. The protocol entails injecting a single solution (1 : 1 CHCl3 : EtOH) containing the halogenated and carbonyl-based substrates into a continuously flowing stream of CHCl3 : EtOH (1 : 1), passed through a fixed bed of K2CO3 and PS-PPh3. With advancement to the previous PS-PPh3 coupling procedures, the method employs a traditional polystyrene-based immobilisation matrix, the substrate scope of the protocol extended to substituted ketones, secondary alkyl chlorides, and an unprotected maleimide scaffold.

Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.