1817-77-2Relevant articles and documents
Formation of Acyclic cis-Azobenzene without Light
Tamaoki, Nobuyuki,Yoshimura, Sawako,Yamaoka, Tsuguo
, p. 2011 - 2012 (1991)
Reduction mixture of bis(4-nitrobenzyl) ether contained a considerable amount of cis-4,4'-dimethylazobenzene.
Palladium and Nickel Catalyzed Suzuki Cross-Coupling with Alkyl Fluorides
Balaraman, Kaluvu,Wolf, Christian
supporting information, p. 8994 - 8999 (2021/11/20)
Suzuki cross-coupling of benzylic and unactivated aliphatic fluorides with aryl- and alkenylboronic acids has been achieved via mechanistically distinct Pd and Ni catalyzed pathways that outperform competing protodeboronation, β-hydride elimination, and h
Dual copper- and photoredox-catalysed C(sp2)-C(sp3) coupling
McLean, Euan B.,Gauchot, Vincent,Brunen, Sebastian,Burns, David J.,Lee, Ai-Lan
supporting information, p. 4238 - 4241 (2019/04/30)
The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp2)-C(sp3) cross-couplings between aryl boronic acids and benzyl bromides.
Decarboxylative Benzylation of Aryl and Alkenyl Boronic Esters
Moon, Patrick J.,Fahandej-Sadi, Anis,Qian, Wenyu,Lundgren, Rylan J.
supporting information, p. 4612 - 4616 (2018/03/26)
The copper-catalyzed decarboxylative benzylation of aryl and alkenyl boronic esters with electron-deficient aryl acetates is reported. The oxidative coupling proceeds under mild, aerobic conditions and tolerates a host of potentially reactive electrophilic functional groups that would be problematic with traditional benzylation methods (aryl iodides and bromides, protic heteroatoms, aldehydes, Michael acceptors). A reaction pathway in which a benzylic nucleophile is generated by aryl acetate decarboxylation and in turn is intercepted by the catalyst to form diarylmethane products is supported by mechanistic studies.