181709-01-3

Basic information

• Product Name: 3-(2-Bromo-cyclohex-1-enylmethyl)-5-trimethylsilanyl-pent-4-yn-1-ol
• CAS NO: 181709-01-3
• Molecular Weight: 329.352
• Mol File: 181709-01-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(2-Bromo-cyclohex-1-enylmethyl)-5-trimethylsilanyl-pent-4-yn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-Bromo-cyclohex-1-enylmethyl)-5-trimethylsilanyl-pent-4-yn-1-ol(181709-01-3)
• EPA Substance Registry System: 3-(2-Bromo-cyclohex-1-enylmethyl)-5-trimethylsilanyl-pent-4-yn-1-ol(181709-01-3)

Safety Data

• Hazardous Substances Data: 181709-01-3(Hazardous Substances Data)

Upstream product

• 13224-84-5 5-trimethylsilanyl-pent-4-yn-1-ol 
• 121898-42-8 (2-Bromocyclohex-1-enyl)methyl bromide 

Downstream Products

• 181709-41-1 3-(2-Bromo-cyclohex-1-enylmethyl)-pent-4-yn-1-ol 

Relevant articles and documents

A new route to γ-arylidenebutyrolactones via a tandem carbopalladation-heterocyclisation sequence: A formal synthesis of U-68,215

Benzo-annulated enol lactones are obtained in good yields from pentynoic acids 3- or 5-substituted with an iodo-aryl moiety by palladium-catalyzed cyclization of their potassium carboxylates. Using this approach, an efficient new route to U-68,215 is described.