181713-52-0

Basic information

• Product Name: 3-Benzyloxy-4-methyl-2-methylene-pentanoic acid methyl ester
• Synonyms: 3-Benzyloxy-4-methyl-2-methylene-pentanoic acid methyl ester
• CAS NO: 181713-52-0
• Molecular Weight: 248.322
• Mol File: 181713-52-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Benzyloxy-4-methyl-2-methylene-pentanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Benzyloxy-4-methyl-2-methylene-pentanoic acid methyl ester(181713-52-0)
• EPA Substance Registry System: 3-Benzyloxy-4-methyl-2-methylene-pentanoic acid methyl ester(181713-52-0)

Safety Data

• Hazardous Substances Data: 181713-52-0(Hazardous Substances Data)

Upstream product

• 71385-30-3 methyl 3-hydroxy-4-methyl-2-methylenepentanoate 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 

Downstream Products

• 181713-64-4 3-Benzyloxy-4-methyl-2-methylene-pentan-1-ol 
• 181713-43-9 (2-Bromomethyl-1-isopropyl-allyloxymethyl)-benzene 
• 152454-43-8 3-Benzyloxy-4-methyl-2-methylene-pentanal 

Relevant articles and documents

13-Asymmetric induction in the aldol reactions of α-methylene-β-alkoxy aldehydes

The aldol reactions of the α-methylene-β-alkoxy aldehydes 3 and 6 were examined for a range of Ti (IV), Sn(II), and B enolates. The sense and level of 1,3-asymmetric induction (up to 95% ds) varies with the enolate structure and the β-hydroxyl protecting

1,4-Asymmetric induction in the Nozaki-Hiyama reaction

A series of allyl bromides 3a-c bearing a stereogenic carbon substituent at C-2 are synthesized in four steps from methyl acrylate. These are found to react with aldehydes, mediated by chromium(II) chloride, to furnish syn-4-alkoxyalkan-1-ols 4 in good to