18192-44-4

Basic information

• Product Name: (4-bromobenzyl)triethylsilane
• Synonyms: (4-bromobenzyl)triethylsilane
• CAS NO: 18192-44-4
• Molecular Weight: 285.299
• Mol File: 18192-44-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-bromobenzyl)triethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-bromobenzyl)triethylsilane(18192-44-4)
• EPA Substance Registry System: (4-bromobenzyl)triethylsilane(18192-44-4)

Safety Data

• Hazardous Substances Data: 18192-44-4(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 19350-68-6 p-bromobenzaldehyde tosylhydrazone 

Downstream Products

• 17898-80-5 1--4-trimethylsilyl-benzol 

Relevant articles and documents

Iron Porphyrin Catalyzed Insertion Reaction of N-Tosylhydrazone-Derived Carbenes into X-H (X = Si, Sn, Ge) Bonds

An efficient Fe(TPP)Cl catalyzed insertion reaction of in situ generated benzylic carbenes from N-tosylhydrazones into X-H (X = Si, Sn, Ge) was developed. Silanes bearing tertiary, secondary, and primary (3°, 2°, and 1°) Si-H bonds all reacted well to afford insertion products in moderate to high yields (up to 97%), and the reaction time could be significantly shortened to 1 h under microwave irradiation. A programmable stepwise double insertion strategy was developed for the synthesis of unsymmetrical tetrasubstituted silanes.