182175-08-2

Basic information

• Product Name: (η(3)-2-SPh-cyclohexenyl)Mo(CO)2(C5H5)
• Synonyms: (η(3)-2-SPh-cyclohexenyl)Mo(CO)2(C5H5)
• CAS NO: 182175-08-2
• Molecular Weight: 406.357
• Mol File: 182175-08-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η(3)-2-SPh-cyclohexenyl)Mo(CO)2(C5H5)(CAS DataBase Reference)
• NIST Chemistry Reference: (η(3)-2-SPh-cyclohexenyl)Mo(CO)2(C5H5)(182175-08-2)
• EPA Substance Registry System: (η(3)-2-SPh-cyclohexenyl)Mo(CO)2(C5H5)(182175-08-2)

Safety Data

• Hazardous Substances Data: 182175-08-2(Hazardous Substances Data)

Upstream product

• 182175-12-8 Mo(CH₃CN)2(Br)(C₆H₈SC₆H₅) 

Downstream Products

• 182175-11-7 (C₅H₅)Mo(CO)2(C₆H₇SC₆H₅)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Mo(CO)2(C₆H₇SC₆H₅)]PF₆ 
• 182175-09-3 (C₅H₅)Mo(CO)2(C₆H₈SO₂C₆H₅) 

Relevant articles and documents

Regio- and stereocontrolled nucleophilic addition reactions of a phenylthio-substituted cyclohexadiene-containing η4-molybdenum cationic complex

The reaction of a new cationic complex, [Cp-(CO)2Mo(η4-2-SPh-C6H7)] +PF6- (3), with carbon and sulfur nucleophiles was found to give in most cases the C-4 addition products 4 in good yield. The X-ray crystal structure of one of the addition products 4b confirms the regio- and stereochemistry of the reaction.