18238-29-4

Basic information

• Product Name: Cyclohexene, 1-ethenyl-6,6-dimethyl-
• CAS NO: 18238-29-4
• Molecular Formula: C10H16
• Molecular Weight: 136.237
• Mol File: 18238-29-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 1-ethenyl-6,6-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 1-ethenyl-6,6-dimethyl-(18238-29-4)
• EPA Substance Registry System: Cyclohexene, 1-ethenyl-6,6-dimethyl-(18238-29-4)

Safety Data

• Hazardous Substances Data: 18238-29-4(Hazardous Substances Data)

Usage

Description

Cyclohexene, 1-ethenyl-6,6-dimethyl-, also known as 1-Ethyl-6,6-dimethylcyclohexene, is a chemical compound with the molecular formula C10H16. It is a clear, colorless liquid characterized by a sweet, floral odor. Cyclohexene, 1-ethenyl-6,6-dimethylis commonly utilized in the production of fragrances and as a flavoring agent in food products due to its pleasant scent.

Uses

Used in Flavor and Fragrance Industry:
Cyclohexene, 1-ethenyl-6,6-dimethylis used as a flavoring agent for its sweet, floral scent in food products, enhancing the sensory experience of consumers.
Cyclohexene, 1-ethenyl-6,6-dimethylis also used as a fragrance ingredient in the production of perfumes, soaps, and cosmetics, contributing to the creation of pleasant and appealing scents for personal care and home products.
Used in Industrial Processes:
Cyclohexene, 1-ethenyl-6,6-dimethylserves as a solvent in various industrial applications, facilitating processes that require the dissolution of other substances or the alteration of their properties.
Used as a Precursor in Organic Synthesis:
Cyclohexene, 1-ethenyl-6,6-dimethylis utilized as a precursor in the synthesis of other organic compounds, playing a crucial role in the production of a range of chemical products.
Safety Considerations:
It is important to handle Cyclohexene, 1-ethenyl-6,6-dimethylwith care, as it can be irritating to the skin, eyes, and respiratory system if not properly managed. Appropriate safety measures should be taken to minimize potential health risks during its use in various applications.

Upstream product

• 56475-48-0 6-iodo-2,2-dimethylhexanenitrile 
• 583-60-8 2-Methylcyclohexanone 
• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 18238-28-3 1-ethenyl-2,2-dimethyl-cyclohexanol 
• 119840-73-2 methyl 6,6-dimethyl-1-cyclohexanecarboxylate 
• 71135-95-0 methyl 2,2-dimethyl-6-oxocyclohexanecarboxylate 
• 53067-23-5 methyl 7-methyl-3-oxooct-6-enoate 
• 115463-65-5 6,6-dimethyl-1-cyclohexenecarboxaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 99978-28-6 methyl 6-hydroxy-2,2-dimethylcyclohexanecarboxylate 
• 110-93-0 6-Methyl-hept-5-en-2-on 

Downstream Products

• 1370028-09-3 C₅₁H₇₀O₅ 
• 1370028-03-7 C₄₉H₆₂O₄ 
• 1370028-08-2 C₄₉H₆₂O₄ 
• 1271725-42-8 (4aR,5R,6E,9E)-5-(2,5-dimethoxyphenyl)-1,1-dimethyl-2,3,4,4a,5,8-hexahydro-1H-benzo[7]annulen-6-yl pivalate 
• 119400-86-1 salviolone 
• 25045-21-0 3-Methoxy-8,8-dimethyl-4a,4b,5,6,7,8,10,10a-octahydro-phenanthrene-1,4-dione 
• 93126-30-8 3-Eth-(E)-ylidene-4,4-dimethyl-cyclohexene 
• 568-72-9 tanshinone-IIA 
• 118950-00-8 3,8,8-Trimethyl-8,9,10,11-tetrahydro-phenanthro[4,3-b]furan-4,5-dione 

Relevant articles and documents

Platinum-catalyzed α,β-unsaturated carbene formation in the formal syntheses of frondosin B and liphagal

Formal syntheses of tetracyclic terpenoids frondosin B and liphagal are described. Both synthetic routes rely on the use of platinum-catalyzed α,β-unsaturated carbene formation for the key C-C bond forming transformations. The successful route toward frondosin B utilizes a formal (4 + 3) cycloaddition, while the liphagal synthesis features the vinylogous addition of an enol nucleophile as a key step. Both synthetic routes are discussed, revealing insights into structural requirements in the catalytic a,β-unsaturated carbene reaction manifold.

Total synthesis of (+/-)-frondosin B and (+/-)-5-epi-liphagal by using a concise (4+3) cycloaddition approach

A recently developed (4+3) cycloaddition between dienes and furfuryl alcohols, as precursors of oxyallyl-type cations, has been used as a key step in the racemic syntheses of two natural products: frondosin B and liphagal. This work demonstrates the synthetic potential of this cycloaddition reaction, and offers a short synthetic route to an interesting family of natural products. A full account of these synthetic studies is presented, further illustrating the mechanism, scope, and limitations of this straightforward synthetic method for seven-membered rings. Cycloheptanes: Furfuryl alcohols serve as effective three-carbon dienophiles for a wide range of dienes in stereoselective cycloaddition reactions. This efficient reaction has been used to prepare two cycloheptanoid natural products, offering a conceptually straightforward and short synthetic entry into a biologically interesting class of polycyclic meroterpenoids (see scheme; TFA = trifluoroacetic acid). Copyright

Synthesis of (±)-nosyberkol (isotuberculosinol, revised structure of edaxadiene) and (±)-tuberculosinol

Me2AlCl-catalyzed Diels-Alder reaction of N-tigloyloxazolidinone with 6,6-dimethyl-1-vinylcyclohexene selectively provided the exo adduct, which was converted to nosyberkol (isotuberculosinol) and tuberculosinol. The spectral data for nosyberko