183233-93-4

Basic information

• Product Name: methyl 2-oxo-1-phenylcyclopentane-1-carboxylate
• Synonyms: methyl 2-oxo-1-phenylcyclopentane-1-carboxylate
• CAS NO: 183233-93-4
• Molecular Weight: 218.252
• Mol File: 183233-93-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 2-oxo-1-phenylcyclopentane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-oxo-1-phenylcyclopentane-1-carboxylate(183233-93-4)
• EPA Substance Registry System: methyl 2-oxo-1-phenylcyclopentane-1-carboxylate(183233-93-4)

Safety Data

• Hazardous Substances Data: 183233-93-4(Hazardous Substances Data)

Upstream product

• 10472-24-9 methyl 2-oxocyclopentane-1-carboxylate 
• 98-80-6 phenylboronic acid 
• 536-80-1 iodosylbenzene 

Downstream Products

• 1048671-14-2 C₁₆H₂₂O₃Si 

Relevant articles and documents

The influence of ligands in Pinhey phenylation reactions using lead(IV) tetracarboxylates

Lead(IV) tetracarboxylates, prepared from achiral and chiral carboxylic acids, have been shown to undergo metal-metal exchange with phenylboronic acid, and the phenyllead(IV) carboxylates thus generated in situ can be used for Pinhey phenylation reactions

Synthesis of methyl 1-aryl-2-oxo-cycloalkanecarboxylates via tricarbonylchromium complexes under mild conditions

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α-Vinylation of 1,3-Dicarbonyl Compounds with Alkenyl(aryl)iodonium Tetrafluoroborates: Effects of Substituents on the Aromatic Ring and of Radical Inhibitors

Direct α-vinylations of enolate anions derived from 1,3-dicarbonyl compounds with 4-teri-butyl-1- cyclohexenyl(aryl)iodonium 2 and 1-cyclopentenyl(aryl)iodonium tetrafluoroborates 3 are reported. Frequently, α-phenylations compete with the vinylations in the reaction of 1,3-dicarbonyl compounds with alkenyl(phenyl)iodonium salts 2a and 3a. Use of alkenyl(p-methoxyphenyl)iodonium salts 2b and 3b, however, leads to selective α-vinylation at the expense of the competing arylation of 1,3-dicarbonyl compounds. Use of an efficient aryl radical trap, 1,1-diphenylethylene, inhibits radical-induced decomposition of the alkenyl(aryl)iodonium salts, thereby improving the yields of α-vinylations of enolate anions derived from 1,3-dicarbonyl compounds.