183617-31-4

Basic information

• Product Name: Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)⁽¹⁺⁾*BF₄^(1-) = [Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)]BF₄
• CAS NO: 183617-31-4
• Molecular Weight: 626.008
• Mol File: 183617-31-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)⁽¹⁺⁾*BF₄^(1-) = [Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)⁽¹⁺⁾*BF₄^(1-) = [Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)]BF₄(183617-31-4)
• EPA Substance Registry System: Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)⁽¹⁺⁾*BF₄^(1-) = [Cu(P(C₆H₅)3)(C₃H₆N₃(C₃H₇)3)]BF₄(183617-31-4)

Safety Data

• Hazardous Substances Data: 183617-31-4(Hazardous Substances Data)

Upstream product

• 10556-98-6 1,3,5-Triisopropyl-1,3,5-triazacyclohexane 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

The Chemistry of 1,3,5-Triazacyclohexane Complexes, 4. Strained 1,3,5-Triazacyclohexane Complexes of Copper(I) and Copper(II)

In this paper we report on the synthesis and the crystallographic characterization of η3-1,3,5-triazacyclohexane (R3TAC) complexes of copper(I) and copper(II).The complexes 2> (1), (2), Cu(PPh3)>(BF4) (3), and (BF4) (4) were characterized by X-ray crystallography.The highly strained and bent Cu-N bonds are longer than in the corresponding complexes of other amine ligands.One methylene carbon atom of the ring comes close to the copper atom (2.55 - 2.65 Angstroem).However, investigation of the ring deuterated complexes by IR and X-ray crystallography (6>2) showed no clear evidence for attractive C-H-Cu interactions. - Keywords: Triazacyclohexanes; Copper complexes; Triphenylphosphane