18388-03-9 Usage
General Description
2-Chloromethyl-3-trimethylsilyl-1-propene is a specialized chemical compound, typically used in organic synthesis procedures. The structure of this chemical includes a propene chain, with a trimethylsilyl group attached, providing organosilicon properties, and a chloromethyl group, adding the reactivity of chlorine. This molecule often plays a key role in precise biochemical reactions due to its particular structure and reactivity. While it’s not a commonly known or understood compound outside of scientific and industrial circles, within these realms, it might be used for creating useful substances, acting as a building block in the synthesis of more complex molecules. Its usage and handling require careful consideration due to potential health and safety factors. Specific data about its properties, safety measures, and exact applications can be expected to be found in material safety data sheets and specialized chemical databases.
Check Digit Verification of cas no
The CAS Registry Mumber 18388-03-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,3,8 and 8 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 18388-03:
(7*1)+(6*8)+(5*3)+(4*8)+(3*8)+(2*0)+(1*3)=129
129 % 10 = 9
So 18388-03-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H13Br/c1-2-3-4-5-6-7-8-9/h2-5,8H2,1H3
18388-03-9Relevant articles and documents
Radical Allylations with Trimethyl[2-[(tributylstannyl)methyl]-2-propenyl]silane or Trimethyl[2-[(triphenylstannyl)-methyl] -2-propenyl] silane
Clive, Derrick L. J.,Paul, Christine Chua,Wang, Zhongren
, p. 7028 - 7032 (1997)
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THE CERIUM (III) MEDIATED REACTION OF TRIMETHYLSILYLMETHYL MAGNESIUM CHLORIDE WITH ESTERS AND LACTONES: THE EFFICIENT SYNTHESIS OF SOME FUNCTIONALISED ALLYLSILANES OF USE IN ANNULATION REACTIONS
Lee, Thomas V.,Channon, Julia A.,Cregg, Carmel,Porter, John R.,Roden, Frances S.,Yeoh, Helena T-L.
, p. 5877 - 5886 (2007/10/02)
The use of cerium (III) chloride alters the chemoselectivity of the reaction of trimethylsilylmethyl magnesium chloride with ester-acetals and also greatly improves the efficiency of reaction with lactones.In addition it gives improved preparations of the useful intermediates (7), (13), (18), (20) and (22) and gives direct access to the valuable functionalised allylsilanes (1) to (3) of use in annulation reactions.
Convenient Alternative Approach to 2-(Acetoxymethyl)-3-(trimethylsilyl)propene
Trost, Barry M.,Buch, Michael,Miller, Maria L.
, p. 4887 - 4888 (2007/10/02)
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