183997-46-8

Basic information

• Product Name: 1-Nitro-4-(2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyloxy)-benzene
• Synonyms: 1-Nitro-4-(2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyloxy)-benzene
• CAS NO: 183997-46-8
• Molecular Weight: 421.167
• Mol File: 183997-46-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Nitro-4-(2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyloxy)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Nitro-4-(2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyloxy)-benzene(183997-46-8)
• EPA Substance Registry System: 1-Nitro-4-(2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyloxy)-benzene(183997-46-8)

Safety Data

• Hazardous Substances Data: 183997-46-8(Hazardous Substances Data)

Upstream product

• 100-02-7 4-nitro-phenol 
• 168632-11-9 2,2,3,3,4,4,5,5,6,6,6-undecafluorohexyl trifluoromethanesulfonate 
• 423-46-1 perfluorohexanol 
• 307-24-4 undecafluorohexanoic acid 

Relevant articles and documents

Various synthetic approaches to fluoroalkyl p-nitrophenyl ethers

Homologous 1H,1H-perfluoroalkyl p-nitrophenyl ethers (alkyl = C2-C8) were synthesized using different methods. The results are discussed in context with contradictory comments of the literature. The fluoroalkoxylation of p-chloronitrobenzene occurs in only one step, but it is limited to small fluoroalkyl groups. The fluoroalkylation of p-nitrophenol via sulphonic acid esters is a better synthetic route. Differences in reactivity and yield between tosylates, mesylates and inflates are found and discussed. The preferred synthesis includes the use of trifluoromethane sulphonic acid esters.