18406-01-4Relevant articles and documents
Photocatalyzed cross-dehydrogenative coupling of silanes with alcohols and water
Lv, Haiping,Laishram, Ronibala Devi,Chen, Jingchao,Khan, Ruhima,Zhu, Yuanbin,Wu, Shiyuan,Zhang, Jianqiang,Liu, Xingyuan,Fan, Baomin
supporting information, p. 3660 - 3663 (2021/04/16)
An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed. The reaction proceeded in the presence of Ru(bpy)3Cl2(0.5 mol%) under visible light irradiation in acetonitrile at room temperature. The developed methodology was also applicable for the synthesis of silanols using water as a coupling partner.
Mild synthesis of silyl ethers: Via potassium carbonate catalyzed reactions between alcohols and hydrosilanes
Delucia, Nicholas A.,Das, Nivedita,Vannucci, Aaron K.
, p. 3415 - 3418 (2018/05/23)
A method has been developed for the silanolysis of alcohols using an abundant and non-corrosive base K2CO3 as a catalyst. Reactions between a variety of alcohols and hydrosilanes generate silyl ethers under mild conditions. The use of hydrosilanes leads to the formation of H2 as the only byproduct thus avoiding the formation of stoichiometric strong acids. The mild conditions lead to a wide scope of possible alcohol substrates and good functional group tolerance. Selective alcohol silanolysis is also observed in the presence of reactive C-H bonds, lending this method for extensive use in protection group chemistry.
Activation of silanes by Grubbs' carbene complex Cl2(PCy3)2Ru=CHPh: Dehydrogenative condensation of alcohols and hydrosilylation of carbonyls
Maifeld, Sarah V,Miller, Reagan L,Lee, Daesung
, p. 6363 - 6366 (2007/10/03)
This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs' catalyst Cl2(PCy3)2Ru=CHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative conde
