18415-17-3Relevant articles and documents
Extended Solution-phase Peptide Synthesis Strategy Using Isostearyl-Mixed Anhydride Coupling and a New C-Terminal Silyl Ester-Protecting Group forN-Methylated Cyclic Peptide Production
Cary, Douglas R.,Handa, Michiharu,Kobayashi, Yutaka,Kurasaki, Haruaki,Masuya, Keiichi,Matsuda, Ayumu,Mimori, Yuji,Murase, Shota,Nagaya, Akihiro,Nishizawa, Naoki,Wakui, Kazuya,Yoshino, Madoka
, p. 2029 - 2038 (2021)
Herein, we present a new and efficient convergent solution-phase synthetic strategy for producing peptides containingN-methyl amino acids. Specifically, we have synthesized a model cyclic octapeptide with twoN-methyl amino acids, utilizing an isostearyl-m
Photochemical functionalizations of C60 with phenylpolysilanes
Kusukawa, Takahiro,Ando, Wataru
, p. 11 - 22 (2007/10/03)
Photolyses of tert-butyl substituted disilanes 1a-1c, and 1i with C60 result in the formation of 1,16-adduct 2 through silyl radical addition to fullerene. The unusual products, 3, 5, 6 and 7 where the silyl and phenyl groups attached on 1,2-positions of fullerene are also obtained from the reaction of 1d-g and 4. The structures of all these compounds were determined by one- and two-dimensional NMR techniques.
On the Generation of Silaethenes of the Types R2Si=CH(SiR3) and R2Si=CH2 by Thermal Salt Elimination and on the Knowledge of R2Si=CH(SitBu3) (R = Me, tBu) [1]
Wiberg, Nils,Finger,Passler,Wagner,Polborn
, p. 1744 - 1760 (2007/10/03)
The generation of silaethenes Me2Si=CH(SiMe3) (1), Me2Si=CH(SitBu3) (2), tBuMeSi=CH(SitBu3) (3), and tBu2Si=CH2 (4) from metal organyls >SiX-CM (X = Br, F; M = Na, Li) by elimin
