184765-68-2

Basic information

• Product Name: Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin]⁽¹⁺⁾
• CAS NO: 184765-68-2
• Molecular Weight: 1313.33
• Mol File: 184765-68-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin]⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin]⁽¹⁺⁾(184765-68-2)
• EPA Substance Registry System: Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin]⁽¹⁺⁾(184765-68-2)

Safety Data

• Hazardous Substances Data: 184765-68-2(Hazardous Substances Data)

Upstream product

• 6156-78-1 manganese (II) acetate tetrahydrate 

Relevant articles and documents

Mn(III)-tetraarylporphyrins bearing covalently bonded crown-ethers: Synthesis and catalytic activity in 1-dodecene epoxidation promoted by aqueous HOCl/OCl-

Mn(III)-complexes of tetraarylporphyrins 1-4 bearing a crown ether covalently linked through a single flexible chain have been synthesized. Their basic frame is that of the robust tetra-(2,6-dichlorophenyl)porphyrin 5 and the chain is connected by ether linkage either to the ortho (1-2) or to the meta positions (3-4) of one meso-aryl group. Catalytic efficiency was tested in the epoxidation of the poorly reactive 1-dodecene at 0°C under CH2Cl2/H2O two-phase conditions in the presence of NaOCl (pH 9.5-10.0) as oxygen donor. The results obtained led us to propose a general acid/base catalysis as an explanation for the positive effect of crown-ethers in the alkene epoxidations with this catalytic system.