18510-49-1

Basic information

• Product Name: Silane, [2,6-bis(1,1-dimethylethyl)-4-methylphenoxy]trimethyl-
• Synonyms: <4-Methyl-2,6-di-tert.-butyl-phenoxy>-trimethyl-silan;3,5-Di-t-butyl-4-trimethylsilyloxytoluene;3,5-Di-tert-butyl-4-trimethylsiloxytoluene;2,6-Di-tert-butyl-4-methylphenol trimethylsilyl ether
• CAS NO: 18510-49-1
• Molecular Formula: C18H32OSi
• Molecular Weight: 292.537
• Mol File: 18510-49-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, [2,6-bis(1,1-dimethylethyl)-4-methylphenoxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [2,6-bis(1,1-dimethylethyl)-4-methylphenoxy]trimethyl-(18510-49-1)
• EPA Substance Registry System: Silane, [2,6-bis(1,1-dimethylethyl)-4-methylphenoxy]trimethyl-(18510-49-1)

Safety Data

• Hazardous Substances Data: 18510-49-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 16654-89-0 sodium 2,6-di-tert-butyl-4-methylphenoxide 
• 97190-47-1 2,6-bis(1,1-dimethylethyl)-4-methylphenyl 2-methylpropanoate 
• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 1433927-32-2 C₂₉H₄₈BiClN₂OSi 
• 1209-80-9 2,6-di-tert-butyl-4-methylphenol potassium salt 

Downstream Products

• 2607-52-5 2,6-di-tert-butyl-4-methylene-2,5-cyclohexadien-1-one 
• 87-97-8 2,6-di-tert-butyl-4-methoxymethylene-phenol 
• 211241-07-5 [4-(Bromomethyl)-2,6-di-tert-butylphenoxy]trimethylsilylane 

Relevant articles and documents

Sterically crowded aryloxide compounds of silicon

The interaction of one equivalent of NaBHT (BHT-H = butylated hydroxytoluene) with Me3SiCl, Me2SiCl2 and SiCl4 gives Me3Si(BHT) (1), Me2SiCl(BHT) (2) and Cl3Si(BHT) (3), respectively, which have been characterized by 1H NMR, IR spectroscopy and elemental

A novel approach towards intermolecular stabilization of para-quinone methides. First complexation of the elusive, simplest quinone methide, 4-methylene-2,5-cyclohexadien-1-one

A novel approach towards the intermolecular stabilization of "simple" (i.e. methylene-unsubstituted) p-quinone methides (QMs) by their coordination to a transition-metal center is described. 4-Bromomethyl phenols, protected by a silyl group, were employed as the QM precursors and cis-chelating diphosphine Pd0 complexes were chosen as the metal precursors, since they have strong back-bonding interactions with the electron-poor QM moiety. Removal of the silyl protecting-group from the corresponding [LPd(benzyl)Br] complex (L=bisphosphine) with fluoride results in the spontaneous rearrangement of the unobserved zwitterionic PdII complex into the QM-Pd0 complex. The feasibility of this approach was demonstrated in the synthesis of the structurally characterized Pd0 complex of BHT-QM (4), a biologically relevant metabolite of 2,6-di-tert-butyl-p-cresol, and the synthesis of the complex of 4-methylene-2,5-cyclohexadien-1-one (11), the simplest, and so far unobserved QM molecule. These complexes exhibit a remarkable thermal stability and do not react with alcohol or water. In both cases, the use of an appropriate incoming ligand allowed the release of the coordinated QM into the reaction media in which it was effectively trapped by added nucleophiles.