18516-37-5Relevant articles and documents
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Shono,T. et al.
, p. 2807 - 2810 (1978)
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Simple, chemoselective, catalytic olefin isomerization
Crossley, Steven W. M.,Barabé, Francis,Shenvi, Ryan A.
supporting information, p. 16788 - 16791 (2015/01/09)
Catalytic amounts of Co(SaltBu,tBu)Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
Iron thiolate complexes: Efficient catalysts for coupling alkenyl halides with alkyl grignard reagents
Cahiez, Gerard,Gager, Olivier,Buendia, Julien,Patinote, Cindy
supporting information; experimental part, p. 5860 - 5863 (2012/07/01)
Ironing out the kinks: Efficient new catalytic systems based on iron thiolates are described for the iron-catalyzed cross-coupling of alkyl Grignard reagents with alkenyl halides (see scheme). The reaction is highly chemo- and stereoselective. With this new procedure, the use of N-methylpyrrolidone as a co-solvent is no longer required. Copyright