185406-04-6

Basic information

• Product Name: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride
• Synonyms: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride
• CAS NO: 185406-04-6
• Molecular Weight: 545.42
• Mol File: 185406-04-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride(185406-04-6)
• EPA Substance Registry System: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride(185406-04-6)

Safety Data

• Hazardous Substances Data: 185406-04-6(Hazardous Substances Data)

Upstream product

• 202277-68-7 bis[N,N′-(2,6-diimethylphenyl)imino]acenaphthene 

Downstream Products

• 851539-79-2 N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate 
• 851539-99-6 N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(κ2-C(Me)(Et)(OAc)) hexafluoroantimonate 
• 851539-93-0 N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(κ2-CH(OAc)iPr) hexafluoroantimonate 
• 851539-90-7 N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(κ2-CH(OAc)nPr) hexafluoroantimonate 
• 851539-74-7 N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide 

Relevant articles and documents

Palladium-Catalyzed Ethylene/Methyl Acrylate Cooligomerization: Effect of a New Nonsymmetric α-Diimine

A new nonsymmetric bis(aryl-imino)acenaphthene (Ar-BIAN) ligand, featured by a subtle steric and electronic unbalance of the N-donor atoms, is reported. With the new ligand and the corresponding symmetrically substituted derivatives, both neutral and monocationic Pd-CH3 compounds have been synthesized and characterized. The series of the monocationic complexes [Pd(CH3)(L)(Ar-BIAN)][PF6] (L=CH3CN, dmso) has been extended to dimethyl sulfoxide derivatives. The monocationic complexes are tested as precatalysts for the ethylene/methyl acrylate cooligomerization under mild reaction conditions of temperature and ethylene pressure. The catalytic product is a mixture of ethylene/acrylate cooligomers and higher alkenes. The catalysts containing the new nonsymmetric ligand are found to be more productive than those with the symmetric Ar-BIANs. The Pd-dmso catalysts are more productive and show a longer lifetime than their Pd-NCCH3 counterparts.