185543-98-0

Basic information

• Product Name: [(1',2,2',3,3',4,4',5-octamethylferrocenyl)methyl]triphenylphosphonium bromide
• CAS NO: 185543-98-0
• Molecular Weight: 653.465
• Mol File: 185543-98-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(1',2,2',3,3',4,4',5-octamethylferrocenyl)methyl]triphenylphosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: [(1',2,2',3,3',4,4',5-octamethylferrocenyl)methyl]triphenylphosphonium bromide(185543-98-0)
• EPA Substance Registry System: [(1',2,2',3,3',4,4',5-octamethylferrocenyl)methyl]triphenylphosphonium bromide(185543-98-0)

Safety Data

• Hazardous Substances Data: 185543-98-0(Hazardous Substances Data)

Upstream product

• 128925-13-3 1-(hydroxymethyl)-1',2,2',3,3',4,4',5-octamethylferrocene 
• 6399-81-1 triphenylphosphine hydrobromide 

Downstream Products

• 41311-84-6 1,1',2,2',3,3',4,4',5-nonamethylferrocene 
• 629653-38-9 (1',2,2',3,3',4,4',5-octamethylferrocenyl)methyl-diphenylphosphine oxide 

Relevant articles and documents

Synthesis and electrochemical properties of slipped-cofacial porphyrin dimers of ferrocene-functionalized Zn-imidazolyl-porphyrins as potential terminal electron donors in photosynthetic models

A systematic series of ferrocene-functionalized Zn-imidazolyl-porphyrins were synthesized to assemble into the slipped-cofacial porphyrin dimers through imidazolyl-to-zinc complementary coordination as artificial photosynthetic models. Direct substitution at the meso position of the porphyrin ring with ferrocence and octamethylferrocene leads to the characteristic electronic structures, while the ferrocene substituents through phenylene-ethenylene and phenylene-ethylene spacers mitigate the electronic communications. Bathochromic shift of Q band, fluorescence quenching, and redox potentials of porphyrin ring are rationalized by the degree of electron-donating ability of the terminal ferrocenes. the Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2006.