186135-56-8

Basic information

• Product Name: 2H-1-Benzazepin-2-one,4-ethoxy-1,5-dihydro-(9CI)
• Synonyms: 2H-1-Benzazepin-2-one,4-ethoxy-1,5-dihydro-(9CI)
• CAS NO: 186135-56-8
• Molecular Formula: C12H13NO2
• Molecular Weight: 203.23712
• Product Categories: ETHOXY
• Mol File: 186135-56-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-1-Benzazepin-2-one,4-ethoxy-1,5-dihydro-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1-Benzazepin-2-one,4-ethoxy-1,5-dihydro-(9CI)(186135-56-8)
• EPA Substance Registry System: 2H-1-Benzazepin-2-one,4-ethoxy-1,5-dihydro-(9CI)(186135-56-8)

Safety Data

• Hazardous Substances Data: 186135-56-8(Hazardous Substances Data)

Upstream product

• 73818-55-0 Bestmann ylide 
• 64460-85-1 o-aminophenylacetic acid ethyl ester 

Relevant articles and documents

Domino syntheses of five-, six- and seven-membered O-, N- and S-heterocycles from α-, β- and γ-substituted carboxylic esters

By a one-pot procedure, tetronic acids, tetronates, coumarins, benzoxepinones and their N- and S-analogues are readily accessible from keteneylidene(triphenyl)phosphorane 2 and carboxylic esters bearing OH, NHR or SH groups in an α-, β- or γ-position by an addition/Wittig olefination/(Claisen rearrangement) sequence. This cascade can be controlled by temperature variation. Extension of this procedure by a further addition step yielding annulated bisheterocycles such as the furoquinolone 28 is possible in some cases.