186255-41-4Relevant articles and documents
SELECTIVE CARBON-CARBON BOND CLEAVAGE BY EARTH ABUNDANT VANADIUM COMPOUNDS UNDER VISIBLE LIGHT PHOTOCATALYSIS
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, (2016/09/22)
Provided herein a vanadium(V) complex of formula I, where R1 to R8 are as defined herein. Also provided herein are reactions making use of the vanadium(V) complex of formula I, such as selective sp3-sp3 carbon-carbon bond cleavage under visible light photocatalysis and photodegradation of lignin.
Non-oxidative vanadium-catalyzed co bond cleavage: Application to degradation of lignin model compounds
Son, Sunghee,Toste, F. Dean
supporting information; experimental part, p. 3791 - 3794 (2010/08/22)
(Chemical Equation Presented) New direction: Changes In the ligand structure divert the reactivity of vanadium (V) oxo complexes from alcohol oxidation to a novel non-oxidative C-O bond cleavage. Thus, highly functionalized aryl enones can be selectively generated from lignin model compounds by vanadium-catalyzed cleavage of the β-O-4 linkage (see scheme; N blue, O red).