186465-05-4

Basic information

• Product Name: 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene
• Synonyms: 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene
• CAS NO: 186465-05-4
• Molecular Weight: 310.395
• Mol File: 186465-05-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene(186465-05-4)
• EPA Substance Registry System: 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene(186465-05-4)

Safety Data

• Hazardous Substances Data: 186465-05-4(Hazardous Substances Data)

Upstream product

• 573-97-7 1-bromo-2-naphthol 
• 3401-47-6 1-bromo-2-methoxynaphthalene 
• 4688-76-0 2-Biphenylboronic acid 

Downstream Products

• 218961-93-4 4-Biphenyl-2-yl-3-methoxymethoxy-naphthalene-2-carbaldehyde 
• 218961-92-3 1-Biphenyl-2-yl-2-methoxymethoxy-naphthalene 
• 186492-29-5 1-(2-phenylphenyl)-2-naphthol 
• 218961-91-2 Carbonic acid 1-biphenyl-2-yl-naphthalen-2-yl ester (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant articles and documents

Catalytic and highly enantioselective aziridination of styrene derivatives

Highly enantioselective catalytic aziridination of styrene derivatives was realized by using the newly designed (salen)manganese(III) complex as a catalyst.

Phosphine ligand containing benzofuran structure and preparation method and application thereof

The invention discloses phosphine ligand containing a benzofuran structure and a preparation method and application thereof. The phosphine ligand is a compound with a chemical structural formula shown in a formula (I) or an enantiomer or racemate of the compound. According to the phosphine ligand disclosed by the invention, a furan nucleus is introduced, so that electron cloud density of the aromatic nucleus of the phosphine ligand is improved, and steric hindrance is changed; thus, the phosphine ligand has the characteristics of good reaction activity and high yield of 99% when being applied to palladium-catalysis Suzuki-Miyaura model reaction. The phosphine ligand containing the benzofuran structure disclosed by the invention has a simple synthesizing method, is low in cost and is suitable for palladium-catalysis Suzuki-Miyaura reaction of varieties of substances.

Anionic phospho-fries rearrangement at ferrocene: One-pot approach to P,O-substituted ferrocenes

For the first time the anionic phospho-Fries rearrangement has been successfully applied in ferrocene chemistry, giving access to 1,2-P,O-substituted ferrocenes. The 1,3 (O → C)-migration occurs at ferrocenyl phosphates, thiophosphates, phosphite-borane adducts, and phosphinates by treatment with a base such as lithium diisopropylamide at low temperature, whereas the highest yields were obtained starting from diethylferrocenyl phosphate. Complete reduction of the phosphonate to a primary phosphine and subsequent Stelzer P,C cross coupling allowed the synthesis of Fe(η5-C5H3-2-OMe-PPh2) (η5-C5H5) (1). The qualification of 1 as a supporting ligand in palladium-catalyzed Suzuki-Miyaura C,C couplings has been proven by the synthesis of sterically congested tri-ortho-substituted biaryls under mild reaction conditions in good to excellent yields.