18714-37-9Relevant articles and documents
Microwave-Assisted Synthesis and Antimicrobial Activity of 3-(Arylsulfanyl)-4-hydroxy-2H-chromen-2-ones
Anjaiah, Ch.,Nagamani,Abraham Lincoln, Ch.,Ashok
, p. 2149 - 2153 (2018)
An efficient microwave-assisted synthesis of 3-(arylsulfanyl)-4-hydroxy-2H-chromen-2-ones by condensation of arenesulfonohydrazides with 4-hydroxy-2H-chromen-2-one in the presence of iodine is described. The synthesized compounds were characterized by spe
HBr/H2O2-mediated formation of C–S bond with thiosulfates
Zhang, Rongxing,Jin, Shengzhou,Wan, Yuanxing,Lin, Sen,Yan, Zhaohua
, p. 841 - 847 (2018/02/06)
A novel, efficient, and green protocol to construct C–S bond has been developed via HBr/H2O2-mediated sulfenylation of styrenes and 4-hydroxycoumarins leading to unsymmetrical sulfides. Various unsymmetrical sulfides were prepared in one step with moderate to good yields using environmentally-friendly H2O2 as oxidant and HBr as catalyst. Based on the preliminary experimental results, a plausible reaction mechanism was proposed for HBr/H2O2-mediated formation of C–S bond with thiosulfates.
3-thioaryl-4-hydroxycoumarin derivative and synthesis method thereof
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Paragraph 0018, (2018/03/28)
The invention relates to a preparation method of a 3-thioaryl-4-hydroxycoumarin derivative, and belongs to the field of organic synthesis. The preparation method comprises the following steps: with a4-hydroxycoumarin derivative, sulfur powder and an iodobenzene derivative as raw materials, adding a ligand, an alkali source and a catalyst, and reacting in a solvent to obtain the 3-thioaryl-4-hydroxycoumarin derivative. A sulfur source used in the synthesis is cheap, easy to obtain, stable in performance and environment-friendly; the synthesis method is low in cost, high in reaction yield, mildin condition and easy to operate, and is suitable for industrial production. The derivative has potential application in the field of materials and medicines; by the preparation method, a novel way is provided for the synthesis of the 3-thioaryl-4hydroxycoumarin derivative.