18736-43-1

Basic information

• Product Name: 2-Propenoic acid, 3-phenyl-, 4-nitrophenyl ester
• CAS NO: 18736-43-1
• Molecular Formula: C15H11NO4
• Molecular Weight: 269.257
• Mol File: 18736-43-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-phenyl-, 4-nitrophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-phenyl-, 4-nitrophenyl ester(18736-43-1)
• EPA Substance Registry System: 2-Propenoic acid, 3-phenyl-, 4-nitrophenyl ester(18736-43-1)

Safety Data

• Hazardous Substances Data: 18736-43-1(Hazardous Substances Data)

Upstream product

• 100-02-7 4-nitro-phenol 
• 102-92-1 cinnamoyl chloride 
• 621-82-9 Cinnamic acid 
• 27019-24-5 p-nitrocinnamoyl p-nitro-phenyl ester 
• 77614-06-3 C₁₅H₁₀ClNO₄ 
• 105650-19-9 C₁₆H₁₃NO₄ 
• 71255-82-8 C₁₆H₁₃NO₅ 
• 140-10-3 (E)-3-phenylacrylic acid 

Downstream Products

• 100-02-7 4-nitro-phenol 
• 24561-34-0 C₁₃H₁₃NO₃ 
• 27019-24-5 p-nitrocinnamoyl p-nitro-phenyl ester 
• 77614-06-3 C₁₅H₁₀ClNO₄ 
• 105650-19-9 C₁₆H₁₃NO₄ 
• 71255-82-8 C₁₆H₁₃NO₅ 
• 17895-71-5 p-nitrophenyl hydrocinnamate 
• 942619-29-6 C₁₈H₁₆O₄ 
• 942619-30-9 C₁₅H₁₁ClO₂ 
• 73789-34-1 cinnamic acid 4-chlorophenyl ester 
• 2757-04-2 phenyl cinnamate 
• 99429-99-9 4-methylphenyl cinnamate 

Relevant articles and documents

Isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters

A protocol for the isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters using Hantzsch ester has been developed. Good to excellent yields are observed using α,β-unsaturated aryl esters bearing electron-withdrawing β-subs

Kinetic study on aminolysis of aryl X-substituted-cinnamates in acetonitrile: Differential medium effect determines reactivity and reaction mechanism

A kinetic study on nucleophilic substitution reactions of 2,4-dinitrophenyl X-substituted-cinnamates (1a-1f) and Y-substituted-phenyl cinnamates (2a-2g) with a series of alicyclic secondary amines in MeCN at 25.0 ± 0.1 °C is reported. The Br?nsted-type pl

Molecular iodine catalyst promoted synthesis of chromans and 4-aryl-3,4-dihydrobenzopyran-2-ones via [3+3] cyclocoupling

Molecular iodine as an inexpensive catalyst is described in the construction of 2-substituted or 2,2-disubstituted chromans and 4-aryl-3,4-dihydrobenzopyran-2-ones via [3+3] cyclocoupling. For the synthesis of chromans, phenols and allylic alcohols were refluxed in chloroform in presence of 20 mol % I2 while [3+3] cyclocoupling of phenols and cinnamic acids proceeded to give 4-aryl-3,4-dihydrobenzopyran-2-ones using 30 mol % I2. Later reaction occurs via a tandem hydroarylation- esterification process at 120-130°C under solvent free conditions. Chromans were obtained in 20-92% yields and substituted 4-aryl-3,4-dihydrobenzopyran-2- ones were obtained in 5-85% yields.