18751-39-8

Basic information

• Product Name: (C₆H₅)3Si(OC₄H₉-t)
• Synonyms: (C₆H₅)3Si(OC₄H₉-t)
• CAS NO: 18751-39-8
• Molecular Weight: 332.517
• Mol File: 18751-39-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (C₆H₅)3Si(OC₄H₉-t)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)3Si(OC₄H₉-t)(18751-39-8)
• EPA Substance Registry System: (C₆H₅)3Si(OC₄H₉-t)(18751-39-8)

Safety Data

• Hazardous Substances Data: 18751-39-8(Hazardous Substances Data)

Upstream product

• 76-86-8 Triphenylsilyl chloride 
• 75-65-0 tert-butyl alcohol 
• 4158-64-9 1,1,1,3,3,3-hexaphenyl-disilazane 
• 1450-23-3 hexaphenyldisilane 
• 865-47-4 potassium tert-butylate 
• 789-25-3 HSiPh₃ 
• 791-31-1 triphenylhydroxysilane 

Downstream Products

• 379-50-0 triphenylsilyl fluoride 

Relevant articles and documents

An Efficient Catalyst for the Conversion of Hydrosilanes to Alkoxysilanes

The copper(I) hydride 6 is an efficient catalyst for the alcoholysis of primary and secondary silanes.The reactions proceed at room temperature within a few hours and give the alkoxysilanes in high yields.Only with bulky alcohols or silanes are longer reaction times and/or increased temperatures required.The presence of air accelarates the reactions and gives rise to higher yields of alkoxysilanes, particularly with bulky alcohols.Diols react with PhRSiH2 (R = Me, Ph) to afford 1,3-dioxo-2-silacycloalkanes and with tertiary silanes to furnish the bissilylated diols.When unsaturated alcohols (2-propen-1-ol or 2-propyn-1-ol) are employed, the double or triple bond is retained. - Keywords: Catalytic silane alcoholysis; Alkoxysilanes

KINETICS OF THE REACTIONS OF DISALAZANES WITH tert-BUTYL ALCOHOL

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