18758-92-4Relevant articles and documents
Cyclic Metallasiloxane Compounds of Ti(IV) and Zr(IV). X-Ray Crystal Structures of a cis-Bis(pyridine) Bis(cyclosiloxy)titanate and a Pyridinelithiated Tris(cyclosiloxy)zirconate
Hossain, M. Altaf,Hursthouse, Michael B.,Ibrahim, Ali,Mazid, Muhammed,Sullivan, Alice C.
, p. 2347 - 2352 (1989)
The reaction between Si2Ph4O(OLi)2 (1) and TiCl4 in 2:1 or 3:1 molar ratio gave on addition of pyridine (py) the titanatrisiloxane compound 2(py)2>*2C6H5Me (2).Treatment of ZrCl4 with (1) in 1:2 molar ratio gave the zirconadisiloxane
Preparation and Crystal Structure of the Titanaspiroheptasiloxane cis-Bis(Hexaphenyltrisiloxanediolato)dipyridine-titanium Bis(Toluene) Solvate
Hossain, M. Altaf,Hursthouse, Michael B.,Mazid, Muhammed A.,Sullivan, Alice C.
, p. 1305 - 1306 (2007/10/02)
The products isolted in good yield from the reactions of dilithium tetraphenyldisiloxanediolate and (a) titanium tetrachloride (with subsequent addition of pyridine) or (b) dichloro(dimethyl)silane were the cyclic spirotitanaheptasilo