188000-43-3Relevant articles and documents
Asymmetric induction in a new domino reaction of [3,3]-sigmatropic rearrangement of allylic thiocyanates and intramolecular heterocyclisation
Gonda, Jozef,Martinková, Miroslava,Imrich, Ján
, p. 1611 - 1616 (2007/10/03)
A new synthetic route to diastereomerically pure (4S,5S)-4-vinyltetrahydro-1H-2-imidazolethiones via a novel domino reaction of [3,3]-sigmatropic rearrangement of chiral thiocyanates followed by stereoselective intramolecular amine addition to arising isothiocyanates is reported.