18829-59-9

Basic information

• Product Name: 2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol
• Synonyms: 2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol;Einecs 242-610-1
• CAS NO: 18829-59-9
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.35046
• EINECS: 242-610-1
• Mol File: 18829-59-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 309.8°C at 760 mmHg
• Flash Point: 127.6°C
• Appearance: /
• Density: 1.03g/cm³
• Vapor Pressure: 5.61E-05mmHg at 25°C
• Refractive Index: 1.534
• CAS DataBase Reference: 2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol(18829-59-9)
• EPA Substance Registry System: 2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol(18829-59-9)

Safety Data

• Hazardous Substances Data: 18829-59-9(Hazardous Substances Data)

Usage

General Description

2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol is a chemical compound with a complex structure. It is a derivative of azulene, a bicyclic organic compound with a characteristic blue color. The compound has six carbons in the fused rings, with multiple methyl groups attached at different positions. The presence of oxygen in the molecule indicates that it is an alcohol, and the presence of a methano bridge suggests a bridged ring structure. The compound's specific structure and properties make it potentially useful in various applications, such as in the field of fragrances or as a building block for the synthesis of other complex organic compounds. Further research and analysis would be necessary to fully understand and harness the potential of this chemical.

InChI:InChI=1/C15H24O/c1-9-7-13(16)15-8-11(9)14(3,4)12(15)6-5-10(15)2/h7,10-13,16H,5-6,8H2,1-4H3

Upstream product

• 469-61-4 alpha-cedrene 
• 17194-58-0 2-[(1R)-1,5-dimethylhex-4-enyl]-5-methylphenol 
• 146026-86-0 C₁₇H₂₆O₂ 
• 1262998-09-3 cedrenone 
• 1262789-28-5 C₁₇H₂₄O₃ 
• 1262789-27-4 C₁₂H₁₆O₂ 
• 30960-39-5 (8aS)-4-oxo-3c,6,8,8-tetramethyl-(8arH)-1,2,3,7,8,8a-hexahydro-3H-3at,7t-methano-azulene; (-)-cedrenone 
• 22567-49-3 (+)-cedrenene 
• 469-61-4 (-)-α-cedrene 

Relevant articles and documents

Cedar camphor derivative as well as preparation method and application thereof

The invention relates to the technical field of synthetic drugs, in particular to a cedar camphor derivative as well as a preparation method and an application thereof. The cedar camphor derivative isany one of compounds shown in the following structural formula, tautomers, hydrates, solvates or pharmaceutically acceptable salts thereof, and the cedar camphor derivative has a good treatment effect on viruses, especially influenza viruses, so that the application range of the cedar camphor and the derivatives thereof is expanded, and the variety of the cedar camphor derivatives is expanded.

An oxidative dearomatization-induced [5 + 2] cascade enabling the syntheses of α-cedrene, α-pipitzol, and sec -cedrenol

Efficient syntheses of α-cedrene (1), α-pipitzol (2), and sec-cedrenol (3) were carried out using a new method, which was inspired by the proposed biosynthesis of the tricyclic skeleton of cedrol (12). The key transformation begins with the oxidative dearomatization of curcuphenol (5a) followed by an intramolecular [5 + 2] cycloaddition of the respective phenoxonium intermediate across the tethered olefin. The benzylic stereocenter effectively guides the formation of the first two stereocenters during the [5 + 2] reaction. The cascade then terminates with the selective incorporation of acetic acid to generate a third stereocenter, setting it apart from other previous cationic [5 + 2] reactions. The phenolic precursors (5a-h) are constructed from readily available salicylaldehydes, either as the racemate (one pot) or as a specific enantiomer (four pots) by a modification to our method for the generation of ortho-quinone methides (o-QMs).