188302-42-3

Basic information

• Product Name: Benzenemethanamine, N-[1-(1,1-dimethylethyl)-3-butenyl]-
• CAS NO: 188302-42-3
• Molecular Formula: C15H23N
• Molecular Weight: 217.354
• Mol File: 188302-42-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-[1-(1,1-dimethylethyl)-3-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-[1-(1,1-dimethylethyl)-3-butenyl]-(188302-42-3)
• EPA Substance Registry System: Benzenemethanamine, N-[1-(1,1-dimethylethyl)-3-butenyl]-(188302-42-3)

Safety Data

• Hazardous Substances Data: 188302-42-3(Hazardous Substances Data)

Upstream product

• 1775-74-2 N-(2,2-dimethylpropylidene)benzylamine 
• 106-95-6 allyl bromide 
• 26209-45-0 N-benzyl-2,2-dimethylpropanamide 
• 1730-25-2 allylmagnesium bromide 
• 3282-30-2 pivaloyl chloride 
• 100-46-9 benzylamine 
• 1775-74-2 N-(2,2-dimethylpropylidene)benzylamine 
• 2622-05-1 allylmagnesium bromide 
• 2551-83-9 allyltrimethoxysilane 

Relevant articles and documents

Iridium-Catalyzed Reductive Alkylations of Secondary Amides

Reported herein is the first direct, metal-catalyzed reductive functionalization of secondary amides to give functionalized amines and heterocycles. The method is shown to have exceptionally broad scope with respect to suitable nucleophiles, which cover both hard and soft C nucleophiles as well as a P nucleophile. The reaction exhibits good chemoselectivity and tolerates several sensitive functional groups.

A general catalytic allylation using allyltrimethoxysilane

A general and mild catalytic allylation of carbonyl compounds, applicable to aldehydes, ketones, and imines is developed using allyltrimethoxysilane as the allylating reagent. The reaction proceeds smoothly with 1-10 mol % of CuCl and TBAT in THF at ambie

Synthesis of azetidines by electrophilic selenium-induced cyclization of homoallylic benzylamines

Homoallyl benzylamines prepared by allylation of the corresponding N-benzylimines, have been subjected to a selenium-induced cyclization under various conditions. At room temperature. the 4-exo and the 5-endo modes are competitive. In acetonitrile, the azetidine has been isolated as the major cyclization product, especially for homoallylamines derived from ketimines. With an excess or selenium reagent, 3-halopyrrolidines have been obtained.